2-(4-Bromo­phen­yl)-5-fluoro-3-phenyl­sulfinyl-1-benzofuran

نویسندگان

  • Hong Dae Choi
  • Pil Ja Seo
  • Byeng Wha Son
  • Uk Lee
چکیده

In the title compound, C(20)H(12)BrFO(2)S, the O atom and the phenyl group of the phenyl-sulfinyl substituent lie on opposite sides of the plane through the benzofuran fragment; the phenyl ring is nearly perpendicular to this plane [dihedral angle = 86.98 (6)°]. The 4-bromo-phenyl ring is rotated slightly out of the benzofuran plane, making a dihedral angle of 1.56 (8)°. The crystal structure features aromatic π-π inter-actions between the furan and phenyl rings of neighbouring mol-ecules [centroid-centroid distance = 3.506 (3) Å], and an inter-molecular C-H⋯π inter-action. The crystal structure also exhibits a short inter-molecular S⋯S contact [3.2635 (8) Å].

برای دانلود رایگان متن کامل این مقاله و بیش از 32 میلیون مقاله دیگر ابتدا ثبت نام کنید

ثبت نام

اگر عضو سایت هستید لطفا وارد حساب کاربری خود شوید

منابع مشابه

5-Chloro-2-(4-fluoro­phen­yl)-3-phenyl­sulfinyl-1-benzofuran

In the title compound, C(20)H(12)ClFO(2)S, the O atom and the phenyl ring of the phenyl-sulfinyl substituent lie on opposite sides of the plane of the benzofuran fragment; the phenyl ring is almost perpendicular to this plane [82.44 (5)°]. The 4-fluoro-phenyl ring is rotated out of the benzofuran plane, making a dihedral angle of 20.83 (6)°.

متن کامل

5-Bromo-2-(4-fluoro­phen­yl)-3-phenyl­sulfinyl-1-benzofuran

In the title compound, C(20)H(12)BrFO(2)S, the 4-fluoro-phenyl ring makes a dihedral angle of 2.63 (6)° with the mean plane of the benzofuran fragment. The dihedral angle between the phenyl ring and the mean plane of the benzofuran fragment is 84.60 (6)°. In the crystal, mol-ecules are linked by weak inter-molecular C-H⋯O hydrogen bonds, and slipped π-π inter-actions between the benzene rings o...

متن کامل

2-(4-Fluoro­phen­yl)-5,6-methyl­enedi­oxy-3-phenyl­sulfinyl-1-benzofuran monohydrate

In the title compound, C(21)H(13)FO(4)S·H(2)O, the dihedral angles between the mean plane of the benzofuran fragment (r.m.s. deviation = 0.005 Å) and the pendant 4-fluoro-phenyl and phenyl rings are 6.24 (7) and 83.39 (6)°, respectively. In the crystal, mol-ecules are linked by O-H⋯O and C-H⋯O hydrogen bonds.

متن کامل

2-(4-Fluoro­phen­yl)-5-iodo-3-phenyl­sulfinyl-1-benzofuran

In the title compound, C(20)H(12)FIO(2)S, the dihedral angles between the mean plane [r.m.s. deviation = 0.014 (1) Å] of the benzofuran fragment and the pendant 4-fluoro-phenyl and phenyl rings are 8.0 (1) and 86.06 (6)°, respectively. In the crystal, mol-ecules are linked by weak C-H⋯O hydrogen bonds. The crystal structure also exhibits weak π-π inter-actions between the furan and benzene ring...

متن کامل

2-(4-Bromo­phen­yl)-5,6-methyl­enedi­oxy-3-phenyl­sulfinyl-1-benzofuran benzene solvate

In the title compound, C(21)H(13)BrO(4)S·C(6)H(6), the O atom and the phenyl group of the phenyl-sulfinyl substituent are located on opposite sides of the mean plane of the 5,6-methyl-enedioxy-benzofuran fragment; the phenyl ring is almost perpendicular to this plane [83.66 (6)°]. The 4-bromo-phenyl ring is rotated slightly out of the 5,6-methyl-enedioxy-benzo-furan plane, making a dihedral ang...

متن کامل

ذخیره در منابع من


  با ذخیره ی این منبع در منابع من، دسترسی به آن را برای استفاده های بعدی آسان تر کنید

عنوان ژورنال:

دوره 66  شماره 

صفحات  -

تاریخ انتشار 2010